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Abstract The discovery of systematic differences in the trace element composition of forsteritic olivines in primitive magmas from within-plate, arc and mid-ocean ridge volcanoes engendered much debate about a causal link to the recycling of oceanic crust into the mantle sources of within-plate and arc magmas. Here we address this problem using Cr-spinel bearing, forsteritic (~Fo80–91) olivines from high-Mg# = 50 = 73 [Mg# = molar ratio of Mg/(Mg + Fe2+)*100] arc magmas from the Trans-Mexican Volcanic Belt (TMVB). The TMVB arc front olivines have similar high Ni, low MnO, and low Mn/Fe as forsteritic olivines from within-plate basalts erupting through thick lithosphere (= WPB-thick). However, the olivines in TMVB arc front primary melts crystallize at much lower temperatures of $${T}_{\mathrm{cryst}}^{\mathrm{oliv}}$$~1119 ± 38 °C (calculated with olivine–spinel aluminum exchange thermometry) in hydrous (~4–9 wt % H2O), silicic, less magnesian (≤10 wt % MgO) mantle melts from mostly garnet-free mantle sources. Model calculations suggest that the primary arc front melts last equilibrated in the mantle at pressures of ~1.4 to ~1.9 GPa (~51–69 km depth) and low temperatures (Tsource = 1150 ± 45 °C) that are only slightly higher than the olivine crystallization temperatures. While the $${\mathrm{Kd}}_{\mathrm{oliv}/\mathrm{melt}}^{\mathrm{Ni}}$$ increases in the cooler and silicic melts, such modulation cannot account for the full range of Ni concentration in TMVB magmatic olivines. A small population of very high-Ni olivines (>4000–5500 μg/g Ni) is best explained by crystallization in Ni-rich components melt that formed by melt rock reaction processes in the mantle wedge. Unlike Ni, olivine MnO is not sensitive to melt temperature and only moderately to melt composition, and thus retains mantle source characteristics. In the TMVB, olivine Fo-MnO-Mn/Fe systematics record an ambient mantle wedge (= mantle without slab component) that is similar to WPB sources and that is variably depleted by slab flux-driven melt extraction. Overall, the olivine Fo-Ni-MnO systematics confirm with greater detail than possible by bulk rock studies that the TMVB primary melts are hydrous and silicic and originate from a mantle wedge that is strongly and variably modified by the slab flux. These results reaffirm a strong genetic link between slab recycling and the genesis of silicic arc magmas. 

Abstract Siliceous slab-derived partial melts infiltrate the sub-arc mantle and cause rock-melt reactions, which govern the formation of diverse primary arc magmas and lithological heterogeneities. The effect of bulk water content, composition of reactants, and nature of melt infiltration (porous versus channelized) on the rock-melt reactions at sub-arc conditions have been investigated by previous studies. However, the effect of multiple episodes of rock-melt reactions in such scenarios has not been investigated before. Here, we explore mantle wedge modifications through serial additions of hydrous-silicic slab partial melts and whether such a process may ultimately explain the origin of high-Mg# andesites found in arcs worldwide. A series of piston-cylinder experiments simulate a serial addition of silicic slab melts in up to three stages (I through III) at 3 GPa and 800–1050°C, using rock-melt proportions of 75–25 and 50–50. A synthetic KLB-1 and a natural rhyolite (JR-1) represented the mantle and the slab components, respectively. Right from the first rock-melt interaction, the peridotite mantle transforms into olivine-free mica-rich pyroxenites ± amphibole ± quartz/coesite in equilibrium with rhyolitic-hydrous melts (72–80 wt% SiO2 and 40–90 Mg#). The formation of olivine-free pyroxenite seems to be controlled by complex functions of T, P, rock-melt ratio, wedge composition, and silica activity of the slab-melt. Remarkably, the pyroxenites approach a melt-buffered state with progressive stages of rock-melt reactions, where those rhyolitic melts inherit and preserve the major (alkalis, Fe, Mg, Ca) and trace element slab-signature. Our results demonstrate that lithological heterogeneities such as pyroxenites formed as products of rock-melt reactions in the sub-arc mantle may function as melt ‘enablers,’ implying that they may act as pathways that enable the infiltrating melt to retain their slab signature without undergoing modification. Moreover, the density contrast between the products of rock-melt reaction (melts and residues) and the average mantle wedge (~150 to 400 kg/m3) may help forming instabilities and diapiric rise of the slab components into the mantle wedge. However, the fate of the primitive slab-melts seems to be associated with the length of the pathway of mantle interaction which explains the evident wide magma spectrum as well as their degree of slab garnet-signature dilution. This work and the existence of high-Mg# Mexican-trondhjemites indicates that almost pristine slab-melts can make their way up to crustal levels and contribute to the arc magma diversity. 

Abstract We investigated the state of the arc background mantle (i.e. mantle wedge without slab component) by means of olivine CaO and its Cr-spinel inclusions in a series of high-Mg# volcanic rocks from the Quaternary Trans-Mexican Volcanic Belt. Olivine CaO was paired with the Cr# [molar Cr/(Cr + Al) *100] of Cr-spinel inclusions, and 337 olivine+Cr-spinel pairs were obtained from 33 calc-alkaline, high-K and OIB-type arc front volcanic rocks, and three monogenetic rear-arc basalts that lack subduction signatures. Olivine+Cr-spinels display coherent elemental and He–O isotopic systematics that contrast with the compositional diversity of the bulk rocks. All arc front olivines have low CaO (0.135 ± 0.029 wt %) relative to rear-arc olivines which have the higher CaO (0.248 ± 0.028 wt %) of olivines from mid-ocean ridge basalts. Olivine 3He/4He–δ18O isotope systematics confirm that the olivine+Cr-spinels are not, or negligibly, affected by crustal basement contamination, and thus preserve compositional characteristics of primary arc magmas. Variations in melt H2O contents in the arc front series and the decoupling of olivine CaO and Ni are inconsistent with controls on the olivine CaO by melt water and/or secondary mantle pyroxenites. Instead, we propose that low olivine CaO reflects the typical low melt CaO of high-Mg# arc magmas erupting through thick crust. We interpret the inverse correlation of olivine CaO and Cr-spinel Cr# over a broad range of Cr# (~10–70) as co-variations of CaO, Al and Cr of their (near) primary host melts, which derived from a mantle that has been variably depleted by slab-flux driven serial melt extraction. Our results obviate the need for advecting depleted residual mantle from rear- and back-arc region, but do not upset the larger underlying global variations of melt CaO high-Mg# arc magmas worldwide, despite leading to considerable regional variations of melt CaO at the arc front of the Trans-Mexican Volcanic Belt.